Diterpenoides com esqueleto cleistantano de Vellozia aff. carunculares Martius ex Seubert (Velloziaceae)



Título del documento: Diterpenoides com esqueleto cleistantano de Vellozia aff. carunculares Martius ex Seubert (Velloziaceae)
Revue: Quimica nova
Base de datos: PERIÓDICA
Número de sistema: 000198556
ISSN: 0100-4042
Autores: 1



Instituciones: 1Universidade Federal do Rio de Janeiro, Instituto de Quimica, Rio de Janeiro. Brasil
2Universidade de Sao Paulo, Instituto de Biologia, Sao Paulo. Brasil
Año:
Periodo: Sep-Oct
Volumen: 24
Número: 5
Paginación: 619-625
País: Brasil
Idioma: Portugués
Tipo de documento: Artículo
Enfoque: Experimental, descriptivo
Resumen en inglés From the hexane extract of leaves, stem and roots, of Vellozia aff. carunculares, fourteen cleistanthane diterpenoids were detected by HRGC-MS, through the analysis of their fragmentation patterns. Comparison of their MS spectra with those of authentic standards previously isolated from other species of the family Velloziaceae allowed the identification, with a high degree of confidence, of eigth known cleistanthane diterpenoids. Of these, four were isolated and identified from their MS, IR and 1H and 13C NMR spectra, as the known cleistantha-8,11,13-trien-7-one, cleistantha-8,11,13-trien-3,7-dione, cleistantha-1,8,11,13-tetraen-3,7-dione and the first reported 6-a-hydroxy-cleistantha-8,11,13-trien-7-one. The triterpenoid b-amyrin was also isolated
Disciplinas: Química
Palabras clave: Fitoquímica,
Química analítica,
Terpenos,
Vellozia aff. carunculares,
Velloziaceae,
Cleistantano,
Africa,
América del Sur
Keyword: Chemistry,
Analytical chemistry,
Phytochemistry,
Terpenes,
Vellozia aff. Carunculares,
Velloziaceae,
Cleistanthane,
South America,
Africa
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