Diterpenoides com esqueleto cleistantano de Vellozia aff. carunculares Martius ex Seubert (Velloziaceae)



Document title: Diterpenoides com esqueleto cleistantano de Vellozia aff. carunculares Martius ex Seubert (Velloziaceae)
Journal: Quimica nova
Database: PERIÓDICA
System number: 000198556
ISSN: 0100-4042
Authors: 1



Institutions: 1Universidade Federal do Rio de Janeiro, Instituto de Quimica, Rio de Janeiro. Brasil
2Universidade de Sao Paulo, Instituto de Biologia, Sao Paulo. Brasil
Year:
Season: Sep-Oct
Volumen: 24
Number: 5
Pages: 619-625
Country: Brasil
Language: Portugués
Document type: Artículo
Approach: Experimental, descriptivo
English abstract From the hexane extract of leaves, stem and roots, of Vellozia aff. carunculares, fourteen cleistanthane diterpenoids were detected by HRGC-MS, through the analysis of their fragmentation patterns. Comparison of their MS spectra with those of authentic standards previously isolated from other species of the family Velloziaceae allowed the identification, with a high degree of confidence, of eigth known cleistanthane diterpenoids. Of these, four were isolated and identified from their MS, IR and 1H and 13C NMR spectra, as the known cleistantha-8,11,13-trien-7-one, cleistantha-8,11,13-trien-3,7-dione, cleistantha-1,8,11,13-tetraen-3,7-dione and the first reported 6-a-hydroxy-cleistantha-8,11,13-trien-7-one. The triterpenoid b-amyrin was also isolated
Disciplines: Química
Keyword: Fitoquímica,
Química analítica,
Terpenos,
Vellozia aff. carunculares,
Velloziaceae,
Cleistantano,
Africa,
América del Sur
Keyword: Chemistry,
Analytical chemistry,
Phytochemistry,
Terpenes,
Vellozia aff. Carunculares,
Velloziaceae,
Cleistanthane,
South America,
Africa
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