Preparation and phytotoxicity of sorgoleone analogues



Document title: Preparation and phytotoxicity of sorgoleone analogues
Journal: Quimica nova
Database: PERIÓDICA
System number: 000198149
ISSN: 0100-4042
Authors: 1



Institutions: 1Universidade Federal de Vicosa, Departamento de Quimica, Vicosa, Minas Gerais. Brasil
2Universidade Federal de Vicosa, Departamento de Fitotecnia, Vicosa, Minas Gerais. Brasil
Year:
Season: Nov-Dic
Volumen: 24
Number: 6
Pages: 751-755
Country: Brasil
Language: Inglés
Document type: Artículo
Approach: Experimental, descriptivo
English abstract 3,5-Dimethoxybenzylic alcohol was converted into the 2-acetoxy-5-methoxy-3-(pent-1-yl)-1,4-benzoquinone (12), in seven steps, with an overall yield of 14.6%. The natural quinone sorgoleone (1) was isolated from Sorghum bicolor and converted into the corresponding quinone (13) having a saturated side chain. The selective effects of these compounds (1, 12 and 13), at the dose of 5.6 mg of a.i./ g of substrate, on the growth of Cucumis sativus, Lactuca sativa, Desmodium tortuosum, Hyptis suaveolens and Euphorbia heterophylla were evaluated. All three compounds caused some inhibition on the root growth of the test plants (0.0-69.19%) with the aerial parts less affected. The results showed that the triene unit of the sorgoleone side chain is not essential for the phytotoxicity and also the synthetic quinone was as active as the natural product
Disciplines: Química
Keyword: Fitoquímica,
Química orgánica,
Quinonas,
Herbicidas,
Fitotoxicidad,
Toxicidad,
Sorghum bicolor,
Cucumis sativus,
Desmodium tortuosum
Keyword: Chemistry,
Organic chemistry,
Phytochemistry,
Quinones,
Herbicides,
Phytotoxicity,
Toxicity,
Sorghum bicolor,
Cucumis sativus,
Desmodium tortuosum
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