Preparation and phytotoxicity of sorgoleone analogues



Título del documento: Preparation and phytotoxicity of sorgoleone analogues
Revista: Quimica nova
Base de datos: PERIÓDICA
Número de sistema: 000198149
ISSN: 0100-4042
Autores: 1



Instituciones: 1Universidade Federal de Vicosa, Departamento de Quimica, Vicosa, Minas Gerais. Brasil
2Universidade Federal de Vicosa, Departamento de Fitotecnia, Vicosa, Minas Gerais. Brasil
Año:
Periodo: Nov-Dic
Volumen: 24
Número: 6
Paginación: 751-755
País: Brasil
Idioma: Inglés
Tipo de documento: Artículo
Enfoque: Experimental, descriptivo
Resumen en inglés 3,5-Dimethoxybenzylic alcohol was converted into the 2-acetoxy-5-methoxy-3-(pent-1-yl)-1,4-benzoquinone (12), in seven steps, with an overall yield of 14.6%. The natural quinone sorgoleone (1) was isolated from Sorghum bicolor and converted into the corresponding quinone (13) having a saturated side chain. The selective effects of these compounds (1, 12 and 13), at the dose of 5.6 mg of a.i./ g of substrate, on the growth of Cucumis sativus, Lactuca sativa, Desmodium tortuosum, Hyptis suaveolens and Euphorbia heterophylla were evaluated. All three compounds caused some inhibition on the root growth of the test plants (0.0-69.19%) with the aerial parts less affected. The results showed that the triene unit of the sorgoleone side chain is not essential for the phytotoxicity and also the synthetic quinone was as active as the natural product
Disciplinas: Química
Palabras clave: Fitoquímica,
Química orgánica,
Quinonas,
Herbicidas,
Fitotoxicidad,
Toxicidad,
Sorghum bicolor,
Cucumis sativus,
Desmodium tortuosum
Keyword: Chemistry,
Organic chemistry,
Phytochemistry,
Quinones,
Herbicides,
Phytotoxicity,
Toxicity,
Sorghum bicolor,
Cucumis sativus,
Desmodium tortuosum
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