| Journal: | Quimica nova |
| Database: | PERIÓDICA |
| System number: | 000196311 |
| ISSN: | 0100-4042 |
| Authors: | Cardoso, Sheila Pressentin1 Carneiro, Jose Walkimar de Mesquita2 |
| Institutions: | 1Universidade Federal Fluminense, Instituto de Quimica, Niteroi, Rio de Janeiro. Brasil 2Escola Tecnica Federal de Quimica, Rio de Janeiro. Brasil |
| Year: | 2001 |
| Season: | May-Jun |
| Volumen: | 24 |
| Number: | 3 |
| Pages: | 381-389 |
| Country: | Brasil |
| Language: | Portugués |
| Document type: | Artículo |
| Approach: | Teórico |
| English abstract | Aromatic nitration is one of the most relevant class of reactions in organic chemistry. It has been intensively studied by both experimental, including works in the condensed as well as in the gas phase, and theoretical procedures. However, the published results do not seem to converge to an unique mechanism. Electrophilic substitution and electron transfer, in an exclusive way, are both proposed as the main mechanism for the reaction. We review these proposals and discuss the most recent findings |
| Disciplines: | Química |
| Keyword: | Química orgánica, Nitración, Nitración aromática, Sustitución electrofílica, Nitración en fase gaseosa, Transferencia electrónica, Mecanismo Ingold-Hughes |
| Keyword: | Chemistry, Organic chemistry, Nitration, Aromatic nitration, Electrophilic substitution, Nitration in gas phase, Electron transfer, Ingold-Hughes mechanism |
| Full text: | Texto completo (Ver HTML) |
