Distribuição de mercúrio em diferentes solos da Bacia do médio Rio Negro-AM: influência da matéria orgânica no ciclo biogeoquímico do mercúrio



Document title: Distribuição de mercúrio em diferentes solos da Bacia do médio Rio Negro-AM: influência da matéria orgânica no ciclo biogeoquímico do mercúrio
Journal: Quimica nova
Database: PERIÓDICA
System number: 000313407
ISSN: 0100-4042
Authors: 1





Institutions: 1Universidade Estadual Paulista "Julio de Mesquita Filho", Instituto de Quimica de Araraquara, Araraquara, Sao Paulo. Brasil
Year:
Season: Abr
Volumen: 30
Number: 2
Pages: 274-280
Country: Brasil
Language: Portugués
Document type: Artículo
Approach: Aplicado, descriptivo
English abstract Soils play an important role in the biogeochemical cycle of mercury as a sink for and source of this metallic species to atmospheric and hydrological compartments. In the study reported here, various types of soil were evaluated to ascertain the influence of parameters such as pH, organic matter content, Fe, Al, sand, silt, clay, C/H, C/N, C/O atomic ratios, and cation exchange capacity on the distribution of Hg in Amazonia's mid-Negro River basin. The data obtained were interpreted by multivariate exploratory analyses (hierarchical cluster analysis and principal component analysis), which indicated that organic matter plays an important role in mercury uptake in the various soils studied. The soils in floodable areas were found to contain 1.5 to 2.8-fold higher Hg concentrations than those in non-floodable areas. Since these soils are flooded almost year-round, they are less available to participate in redox processes at the soil/atmosphere interface. Hence, floodable areas, which comprise humic-rich soils, accumulate more mercury than non-floodable soils, thus playing an important role in the biogeochemical cycle of Hg in Amazonia's mid-Negro River basin
Disciplines: Geociencias
Keyword: Geoquímica,
Suelos,
Mercurio,
Materia orgánica,
Ciclo biogeoquímico
Keyword: Earth sciences,
Geochemistry,
Soils,
Mercury,
Organic matter,
Biogeochemical cycle
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