Novel Routes to Angular and Linear Triquinanes via Radical Induced Epoxide Fragmentation-H-Abstraction-Cyclization Cascades
Document title: Novel Routes to Angular and Linear Triquinanes via Radical Induced Epoxide Fragmentation-H-Abstraction-Cyclization Cascades
Journal: Journal of the Brazilian Chemical Society
Database: PERIÓDICA
System number: 000310738
ISSN: 0103-5053
Authors: 1
2
Institutions: 1Ohio State University, Department of Chemistry, Columbus, Ohio. Estados Unidos de América
2University of Chicago, Department of Chemistry, Chicago, Illinois. Estados Unidos de América
Year:
Season: Ago
Volumen: 9
Number: 4
Pages: 341-344
Country: Brasil
Language: Inglés
Document type: Artículo
Approach: Experimental
English abstract Reported below are the first two applications of our radical induced epoxide fragmentation-H-abstraction-cyclization sequence to triquinane compounds. This tandem sequence has provided the basis of novel routes to both linear and angular triquinanes
Portuguese abstract Descritas abaixo estão as duas primeiras aplicações de nossa sequencia, fragmentação de epóxido induzida por radicais-abstração de H-ciclização, na preparação de compostos triquinânicos. Estas reações sequenciadas forneceram a base para novas rotas levando a triquinanos lineares e angulares
Disciplines: Química
Keyword: Química orgánica,
Síntesis química,
Triquinano,
Fragmentación de radicales,
Reacción en tándem,
Ciclización transanular
Keyword: Chemistry,
Organic chemistry,
Chemical synthesis,
Triquinane,
Radical fragmentation,
Tandem reaction,
Transannular cyclization
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