| Journal: | Journal of the Brazilian Chemical Society |
| Database: | PERIÓDICA |
| System number: | 000310924 |
| ISSN: | 0103-5053 |
| Authors: | Moreira, Jardel A1 Correa, Arlene G |
| Institutions: | 1Universidade Federal de Sao Carlos, Departamento de Quimica, Sao Carlos, Sao Paulo. Brasil |
| Year: | 2000 |
| Season: | Dic |
| Volumen: | 11 |
| Number: | 6 |
| Pages: | 614-620 |
| Country: | Brasil |
| Language: | Inglés |
| Document type: | Artículo |
| Approach: | Experimental, aplicado |
| English abstract | The pine sawfly, Neodiprion sertifer (Geoffrey) (Hymenoptera: Diprionidae), is a widespread and economically important forest insect in North America, Japan and Europe. It has been demonstrated that the main sex pheromone components of this species are acetate or propionate of 3,7-dimethyl-2-pentadecanol (diprionol). We describe herein an enantioselective synthesis of (2R,3R,7S)-diprionol in 12 steps (7.5% overall yield), starting from commercial (-)-isopulegol |
| Portuguese abstract | A mosca Neodiprion sertifer (Geoffrey) (Hymenoptera: Diprionidae) é uma importante praga em florestas de pinheiro no norte da Europa, Ásia e América do Norte. Os componentes majoritários do feromônio sexual desta espécie são acetatos ou propionatos do 3,7-dimetilpentadecan-2-ol (diprionol). Neste trabalho relatamos a síntese enantiosseletiva do (2R,3R,7S)-diprionol em 12 etapas (7.5% de rendimento total), partindo-se do (-)-isopulegol comercial |
| Disciplines: | Química, Biología |
| Keyword: | Química orgánica, Insectos, Feromonas sexuales, Síntesis enantioselectiva, 3,7-dimetilpentadecan-2-ol, Diprionol, Neodiprion sertifer, Hymenoptera |
| Keyword: | Chemistry, Biology, Organic chemistry, Insects, Sex pheromones, Enantioselective synthesis, 3,7-dimethylpentadecan-2-ol, Diprionol, Neodiprion sertifer, Hymenoptera |
| Full text: | Texto completo (Ver HTML) |
