| Journal: | Ecletica quimica |
| Database: | PERIÓDICA |
| System number: | 000332585 |
| ISSN: | 0100-4670 |
| Authors: | Dziewulska-KuBaczkowska, A1 Ferenc, W1 |
| Institutions: | 1Maria Curie-Sklodowska University, Department of General and Coordination Chemistry, Lublin. Polonia |
| Year: | 2009 |
| Season: | Ene-Mar |
| Volumen: | 34 |
| Number: | 1 |
| Pages: | 63-66 |
| Country: | Brasil |
| Language: | Inglés |
| Document type: | Artículo |
| Approach: | Experimental, aplicado |
| English abstract | The complexes of silver(I) with 2,3-, 2,4-, 2,6-, 3,4-, 3,5-dimethoxy-, and 2,3,4- and 3,4,5-trimethoxybenzoic acid anions have been synthesized and characterized by elemental analysis, IR spectroscopy, thermogravimetric and X-ray studies. Their solubility in water has been also determined at 293K. All analysed complexes were found to be crystalline, anhydrous compounds with low symmetry. The carboxylate groups act as bidentate or monodentate ligands. The thermal stability of compounds has been examined in air in temperature range of 293-1173K. The analysed complexes were found to be stable at room temperature and their solubilities in water at 293K to be in the order of 10-4 mol.dm-3 |
| Disciplines: | Química |
| Keyword: | Química organometálica, Plata, Trimetoxibenzoatos, Estabilidad térmica |
| Keyword: | Chemistry, Organometallic chemistry, Silver, Trimethoxybenzoates, Thermal stability |
| Full text: | Texto completo (Ver HTML) |
