Thermal and spectral properties of di-and trimethoxybenzoates of silver (I)



Título del documento: Thermal and spectral properties of di-and trimethoxybenzoates of silver (I)
Revista: Ecletica quimica
Base de datos: PERIÓDICA
Número de sistema: 000332585
ISSN: 0100-4670
Autors: 1
1
Institucions: 1Maria Curie-Sklodowska University, Department of General and Coordination Chemistry, Lublin. Polonia
Any:
Període: Ene-Mar
Volum: 34
Número: 1
Paginació: 63-66
País: Brasil
Idioma: Inglés
Tipo de documento: Artículo
Enfoque: Experimental, aplicado
Resumen en inglés The complexes of silver(I) with 2,3-, 2,4-, 2,6-, 3,4-, 3,5-dimethoxy-, and 2,3,4- and 3,4,5-trimethoxybenzoic acid anions have been synthesized and characterized by elemental analysis, IR spectroscopy, thermogravimetric and X-ray studies. Their solubility in water has been also determined at 293K. All analysed complexes were found to be crystalline, anhydrous compounds with low symmetry. The carboxylate groups act as bidentate or monodentate ligands. The thermal stability of compounds has been examined in air in temperature range of 293-1173K. The analysed complexes were found to be stable at room temperature and their solubilities in water at 293K to be in the order of 10-4 mol.dm-3
Disciplines Química
Paraules clau: Química organometálica,
Plata,
Trimetoxibenzoatos,
Estabilidad térmica
Keyword: Chemistry,
Organometallic chemistry,
Silver,
Trimethoxybenzoates,
Thermal stability
Text complet: Texto completo (Ver HTML)