| Journal: | Brazilian journal of physics |
| Database: | PERIÓDICA |
| System number: | 000385142 |
| ISSN: | 0103-9733 |
| Authors: | Kesavan, S1 Mathew, Chithra M1 Rajendran, S1 Subbu, C1 Ulaganathan, M2 |
| Institutions: | 1Alagappa University, School of Physics, Karaikudi, Tamil Nadu. India 2Nanyang Technological University, Energy Research Institute, Nanyang. Singapur |
| Year: | 2015 |
| Season: | Feb |
| Volumen: | 45 |
| Number: | 1 |
| Pages: | 19-27 |
| Country: | Brasil |
| Language: | Inglés |
| Document type: | Artículo |
| Approach: | Experimental, aplicado |
| English abstract | Solid polymer electrolytes have attracted considerable attention due to their wide variety of electrochemical device applications. In the present study, the fixed concentration of the salt lithium perchlorate (LiClO4) and various concentrations of poly(ethylene oxide)/poly(vinyl pyrrolidone) (PEO/PVP)-based electrolytes were prepared by solvent casting technique. The structural analysis of the present system shows that the amorphous character of the samples is responsible for the process of ion transport. Fourier transform infrared spectroscopy (FTIR) has been used to characterize the structure of polymer and confirm the complexation between the polymers and salt. The maximum ionic conductivity value is found to be 0.2307 × 10−5 S cm−1 for PEO (90 wt%)/PVP (10 wt%)/LiClO4 (8 wt%) (A1) complex at 303 K (30 °C) |
| Disciplines: | Física y astronomía |
| Keyword: | Física de materia condensada, Electrolitos poliméricos, Conductividad iónica, Luminiscencia, Estabilidad térmica |
| Keyword: | Physics and astronomy, Condensed matter physics, Polymeric electrolytes, Ionic conductivity, Luminescence, Thermal stability |
| Full text: | Texto completo (Ver HTML) |
