| Journal: | Brazilian journal of chemical engineering |
| Database: | PERIÓDICA |
| System number: | 000309054 |
| ISSN: | 0104-6632 |
| Authors: | Luna, A.J1 Nascimento, C.A.O Chiavone-Filho, O2 |
| Institutions: | 1Universidade de Sao Paulo, Escola Politecnica, Sao Paulo. Brasil 2Universidade Federal do Rio Grande do Norte, Departamento de Engenharia Quimica, Natal, Rio Grande do Norte. Brasil |
| Year: | 2006 |
| Season: | Sep |
| Volumen: | 23 |
| Number: | 3 |
| Pages: | 341-349 |
| Country: | Brasil |
| Language: | Inglés |
| Document type: | Artículo |
| Approach: | Experimental, aplicado |
| English abstract | The photodecomposition of hydrogen peroxide was performed in highly saline aqueous medium (60 g.L-1 of NaCl). The Fe3+/H2O2/NaCl/UV system was tested at temperatures from 20 to 50 ºC, while the intervals of concentration of Fe3+ and H2O2 were 1 to 2.5 mM and 230 to 630 mM, respectively. It is known from the literature that chloride is an inhibitor of the oxidation of organic compound in aqueous medium, but this effect has not been observed to be expressive for hydrogen peroxide. Despite this result, experiments were conducted in presence of high concentration of salt (60 g.L-1), emulating the agrochemical process condition. The series of measurements has been evaluated and correlated. Thermal and photochemical dependencies were described satisfactorily by a simplified kinetic model. The apparent activation energy was estimated to be 27.6 kJ.mol-1 |
| Disciplines: | Química |
| Keyword: | Química orgánica, Peróxido de hidrógeno, Fotodescomposición, Radical hidroxilo, Cloruros |
| Keyword: | Chemistry, Organic chemistry, Hydrogen peroxide, Photodecomposition, Hydroxyl radical, Chlorides |
| Full text: | Texto completo (Ver HTML) |
