A comparison of concentration measurement techniques for the estimation of the apparent mass diffusion coefficient



Document title: A comparison of concentration measurement techniques for the estimation of the apparent mass diffusion coefficient
Journal: Brazilian journal of chemical engineering
Database: PERIÓDICA
System number: 000308786
ISSN: 0104-6632
Authors: 1
2

Institutions: 1Universidade do Vale do Paraiba, Sao Jose dos Campos, Sao Paulo. Brasil
2Universidade Federal do Rio de Janeiro, Instituto Alberto Luiz Coimbra de Pos-Graduacao e Pesquisa de Engenharia, Rio de Janeiro. Brasil
Year:
Season: Sep
Volumen: 18
Number: 3
Pages: 253-265
Country: Brasil
Language: Inglés
Document type: Artículo
Approach: Experimental, analítico
English abstract In this article we compare two different techniques to measure the concentration of saline solutions for the identification of the apparent mass diffusion coefficient in soils saturated with distilled water. They are the radiation measurement technique and the electrical conductivity measurement technique. These techniques are compared in terms of measured quantities, sensitivity coefficients with respect to unknown parameters and the determinant of the information matrix. The apparent mass diffusion coefficient is estimated by utilizing simulated measurements containing random errors. The Levenberg-Marquardt method of minimization of the least-squares norm is used as the parameter estimation procedure. The effects of the volume of saline solution injected into the column devised for the experiments on the accuracy of the estimated parameters are also addressed in this article
Disciplines: Química
Keyword: Ingeniería química,
Coeficiente de difusión de masa,
Medición de la radiación,
Conductividad eléctrica
Keyword: Chemistry,
Chemical engineering,
Mass diffusion coeficient,
Radiation measurement,
Electrical conductivity
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