Electro chemical characterization of VXNbYCZ/BiXTiYOZ coatings produced through thermo-reactive diffusion and the sputtering technique



Título del documento: Electro chemical characterization of VXNbYCZ/BiXTiYOZ coatings produced through thermo-reactive diffusion and the sputtering technique
Revue: Revista mexicana de física
Base de datos: PERIÓDICA
Número de sistema: 000397539
ISSN: 0035-001X
Autores: 1
1
1
Instituciones: 1Universidad Nacional de Colombia, Departamento de Física, Bogotá. Colombia
2Universidad Nacional de Colombia, Grupo de Investigación Análisis de Fallas, Integridad y Superficies, Bogotá. Colombia
Año:
Periodo: Mar-Abr
Volumen: 62
Número: 2
Paginación: 138-143
País: México
Idioma: Inglés
Tipo de documento: Artículo
Enfoque: Analítico, teórico
Resumen en inglés We present an experimental study of the structural evolution of a bilayer VX NbY CZ /Bix TiY OZ coating produced via thermo-reactive diffusion (TRD) and the RF sputtering process on D2 steel substrate. The TRD treatments were carried out in a molten mixture consisting of borax, ferro-niobium, ferro-vanadium, and aluminum, at 1313 K for 3 hours, using a resistance-heating furnace. BiXTiYOZ coatings were deposited using RF magnetron sputtering on TRD coatings, in order to carry out a study of the corrosion behavior of this compound. The crystallographic structure of the coatings was determined via X-ray diffraction (XRD), the corrosion resistance was analyzed through the po-tentiodynamic polarization test (Tafel Extrapolation) and electrochemical impedance spectroscopic analysis (EIS). XRD patterns showed that the ternary coating (VNbC2) was preferentially oriented along the [200] direction with a cubic-centered face structure, and the BiXTiYOZ coatings were amorphous. The electrochemical studies showed that the resistance corrosion of the coatings increased with respect to the bare substrate, and that polarization resistance in the bilayer coatings increased with respect to the ternary coatings, suggesting that the titanate has anticorrosive barrier effects
Disciplinas: Física y astronomía,
Química
Palabras clave: Acústica,
Fisicoquímica y química teórica,
Difusión termorreactiva,
Revestimientos de titanato de bismuto,
Resistencia a la corrosión,
Pulverización
Keyword: Physics and astronomy,
Chemistry,
Acoustics,
Physical and theoretical chemistry,
Thermo reactive difussion,
Bismuth titanate coatings,
Corrosion resistance,
Sputtering
Texte intégral: Texto completo (Ver PDF)