| Revue: | Quimica nova |
| Base de datos: | PERIÓDICA |
| Número de sistema: | 000199246 |
| ISSN: | 0100-4042 |
| Autores: | Alcantara, Antonio Flavio de Carvalho1 Barroso, Hileia dos Santos Pilo-Veloso, Dorila |
| Instituciones: | 1Universidade do Amazonas, Instituto de Ciencias Exatas, Manaus, Amazonas. Brasil 2Universidade Federal de Minas Gerais, Instituto de Ciencias Exatas, Belo Horizonte, Minas Gerais. Brasil |
| Año: | 2002 |
| Periodo: | Mar-Abr |
| Volumen: | 25 |
| Número: | 2 |
| Paginación: | 300-311 |
| País: | Brasil |
| Idioma: | Portugués |
| Tipo de documento: | Revisión bibliográfica |
| Enfoque: | Teórico, divulgación |
| Resumen en inglés | Despite the fact that boranes are frequently used in amide reductions, the reaction mechanisms of the involved are note well known. This work presents the results of a bibliographic search on probable amide reduction mechanisms and an analysis of the existing literature. Steric and electronic effects were considered in light of reactivity since it could be concluded that the formation of intermediates and products depends mainly on the substitution patterns of both the boron and nitrogen atoms. Otherwise, results described in the literature for the reactions of boranes, sodium borohydride, lithium aluminum hydride, alkylboranes or haloboranes with others functional groups such as carboxylic acids, esters, ketones and alkenes were analysed with the aim to obtain something about the N-substituted amide reactions employing boranes |
| Disciplinas: | Química |
| Palabras clave: | Química orgánica, Amidas, Reducción de amidas, Boranos, Reducción, Mecanismos |
| Keyword: | Chemistry, Organic chemistry, Amides, Reduction of amides, Boranes, Reduction, Mechanisms |
| Texte intégral: | Texto completo (Ver HTML) |
