Interacao tensoativo/hidrotropo em sistemas aquosos, utilizando ressonancia magnetica nuclear de (Sup 1)H e (Sup 13) C



Título del documento: Interacao tensoativo/hidrotropo em sistemas aquosos, utilizando ressonancia magnetica nuclear de (Sup 1)H e (Sup 13) C
Revue: Quimica nova
Base de datos: PERIÓDICA
Número de sistema: 000196048
ISSN: 0100-4042
Autores: 1


Instituciones: 1Universidade Federal do Rio de Janeiro, Instituto de Macromoleculas, Rio de Janeiro. Brasil
2Petroleo Brasileiro S.A., Centro de Pesquisas e Desenvolvimento, Rio de Janeiro. Brasil
Año:
Periodo: Ene-Feb
Volumen: 24
Número: 1
Paginación: 47-54
País: Brasil
Idioma: Portugués
Tipo de documento: Artículo
Enfoque: Experimental, descriptivo
Resumen en inglés In this work, it was studied the behavior of the nonionic surfactant aqueous solutions, containing or not a hydrotropic agent, by resonance magnetic nuclear (NMR). We have studied monofunctional diblock copolymers of poly(propylene oxide-ethylene oxide) (R-PPO-PEO-OH, where R length is linear C4) as nonionic surfactant and sodium p-toluenesulfonate (NaPTS) as hydrotropic agent. The critical micelle concentration (CMC) of the aqueous copolymer solution was obtained from 1H-NMR. The preliminary study of the interaction between the copolymer, under the unimer and micelle forms, and the hydrotrope, in aqueous solutions, was evaluated by 1H-NMR and 13C-NMR
Disciplinas: Química
Palabras clave: Química analítica,
Química orgánica,
Tensoactivos,
Surfactantes,
Resonancia magnética nuclear,
Carbono 13,
Hidrotropía,
Solución acuosa,
Copolímeros
Keyword: Chemistry,
Analytical chemistry,
Organic chemistry,
Tensoactives,
Surfactants,
Nuclear magnetic resonance,
Carbon 13,
Hydrotropy,
Aquosa solution,
Copolymers
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