Alternativa analitica para especiacao fisico-quimica de mercurio em aguas costeiras tropicais



Título del documento: Alternativa analitica para especiacao fisico-quimica de mercurio em aguas costeiras tropicais
Revue: Quimica nova
Base de datos: PERIÓDICA
Número de sistema: 000199679
ISSN: 0100-4042
Autores: 1

Instituciones: 1Universidade Federal do Ceara, Instituto de Ciencias do Mar, Fortaleza, Ceara. Brasil
2Universidade Federal Fluminense, Departamento de Geoquimica, Niteroi, Rio de Janeiro. Brasil
Año:
Periodo: May-Jun
Volumen: 25
Número: 3
Paginación: 372-378
País: Brasil
Idioma: Portugués
Tipo de documento: Artículo
Enfoque: Experimental, descriptivo
Resumen en inglés The determination of the physical-chemical mercury speciation in tropical coastal waters using the derivatization technique with CVAFS detection was optimized. This methodology is able to separate the elementary, reactive, organic and total mercury phases with low operational costs. The importance of bromide chloride solution, the diluted aqua regia, used as the oxidative solution, and different compositions of the reductive solution of stannous chloride were tested and the better results for coastal waters are presented. The recuperation of the sum of the different phases ranges from 80 to 94% of the total Hg content in duplicates of different marine samples. The optimized methodology permits important studies on the mercury cycle in the coastal environment
Disciplinas: Química,
Ingeniería
Palabras clave: Química analítica,
Ingeniería ambiental,
Mercurio,
Agua,
Análisis de agua,
Aguas costeras
Keyword: Chemistry,
Engineering,
Analytical chemistry,
Environmental engineering,
Mercury,
Water,
Water analysis,
Coastal waters
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