| Revue: | Quimica nova |
| Base de datos: | PERIÓDICA |
| Número de sistema: | 000313168 |
| ISSN: | 0100-4042 |
| Autores: | Fatima, Angelo de1 Robello, Luís Gustavo Pilli, Ronaldo Aloise |
| Instituciones: | 1Universidade Estadual de Campinas, Instituto de Quimica, Campinas, Sao Paulo. Brasil |
| Año: | 2006 |
| Periodo: | Sep |
| Volumen: | 29 |
| Número: | 5 |
| Paginación: | 1009-1026 |
| País: | Brasil |
| Idioma: | Portugués |
| Tipo de documento: | Artículo |
| Enfoque: | Experimental, aplicado |
| Resumen en inglés | The field of chiral catalysis has experienced explosive growth over the last two decades. By now, many of the classical reactions in organic synthesis can be carried out efficiently in asymmetric manner. As one of the fundamental and powerful C-C bond-forming reactions, enantioselective catalytic allylation (ECA) and crotylation (ECC) of aldehydes has attracted considerable attention. In this article, we present an overview about the importance of chiral Lewis acids and bases in catalytic enantioselective addition of allyl- and crotyl metals to aldehydes and the application of this methodology in the total synthesis of natural and non-natural products |
| Disciplinas: | Química |
| Palabras clave: | Química orgánica, Catálisis asimétrica, Aldehídos, Alilación, Crotilación, Acidos de Lewis |
| Keyword: | Chemistry, Organic chemistry, Asymmetric catalysis, Aldehydes, Allylation, Crotylation, Lewis acids |
| Texte intégral: | Texto completo (Ver HTML) |
