Viscosities and excess energy of activation for viscous flow for binary mixtures of tetrahydrofuran with 1-butanol, 2-butanol and 1-chlorobutane at 283.15, 298.15 and 313.15 K



Título del documento: Viscosities and excess energy of activation for viscous flow for binary mixtures of tetrahydrofuran with 1-butanol, 2-butanol and 1-chlorobutane at 283.15, 298.15 and 313.15 K
Revista: Brazilian journal of chemical engineering
Base de datos: PERIÓDICA
Número de sistema: 000308669
ISSN: 0104-6632
Autores: 1


2


Instituciones: 1Universidad Nacional del Comahue, Facultad de Ingeniería, Neuquén. Argentina
2Universidad de Zaragoza, Facultad de Ciencias, Zaragoza. España
Año:
Periodo: Dic
Volumen: 17
Número: 4-7
Paginación: 459-470
País: Brasil
Idioma: Inglés
Tipo de documento: Artículo
Enfoque: Experimental
Resumen en inglés Kinematic viscosities of binary mixtures composed of tetrahydrofuran with 1-butanol, 2-butanol and 1-chlorobutane have been measured at 283.15, 298.15 and 313.15 K and atmospheric pressure for the whole range of compositions. The dynamic viscosity, the excess viscosity and the excess energy of activation for viscous flow were also calculated. The excess viscosity shows negative deviations from ideal behavior for the mixtures tetrahydrofuran with 1-butanol and 2-butanol and a small positive deviation for the binary tetrahydrofuran + 1-chlorobutane system. The experimental results have also been used to test some empirical and semiempirical equations adopted previously to correlate viscosity - composition data
Disciplinas: Química
Palabras clave: Química orgánica,
Viscosidad,
Tetrahidrofurano,
Butanol,
Clorobutano
Keyword: Chemistry,
Organic chemistry,
Viscosity,
Tetrahydrofuran,
Butanol,
Chlorobutane
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