A study on microstructure and magnetic properties of nanostructured CoxNi1-xMn0.5Fe1.5O4 (x = 0,0.25,0.5,0.75,1)spinel ferrites



Document title: A study on microstructure and magnetic properties of nanostructured CoxNi1-xMn0.5Fe1.5O4 (x = 0,0.25,0.5,0.75,1)spinel ferrites
Journal: Revista mexicana de física
Database: PERIÓDICA
System number: 000447218
ISSN: 0035-001X
Authors: 1
2
1
1
3
1
Institutions: 1Khawaja Fareed University of Engineering and Information Technology, Department of Physics, Rahim Yar Khan. Pakistán
2Government College University Faisalabad, Faisalabad. Pakistán
3Bahauddin Zakariya University, Multan. Pakistán
Year:
Season: May-Jun
Volumen: 67
Number: 3
Pages: 527-535
Country: México
Language: Inglés
Document type: Artículo
Approach: Analítico, teórico
English abstract A low-temperature synthesis of novel nanostructured CoxNi1-xMn0.5Fe1.5O4 (x = 0,0.25,0.5,0.75,1) ferrites was carried out by sol-gel auto-combustion technique. The obtained nanostructured ferrites were investigated by employing the techniques of powder X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), energy dispersive X-ray spectroscopy (EDX), and vibrating sample magnetometry (VSM). The XRD diffractograms of the prepared ferrites revealed the formation of a spinel phase with face-centered cubic (fcc) structure belonging to the Fd- 3 ¯ m space group. The average lattice parameter ‘a’ of ferrites exhibited a rise versus a rise in CO2+ concentration following Vegard’s law. The SEM investigation of NiMn0.5Fe1.5O4 powder revealed the existence of octahedral-shaped morphology of ferrite grains. The TEM investigation of NiMn0.5Fe1.5O4 powder showed nanostructures of ferrite particles with sizes consistent with the crystallite sizes as estimated by Debye-Scherer’s formula. An EDX spectrum of NiMn0.5Fe1.5O4 powder confirmed its elemental composition. The M-H hysteresis loops recorded by VSM at room temperature revealed a dependence of coercivity (Hc), maximum magnetization (Mmax), and retentivity (Mr) on CO2+ concentration. The shape dependence of M-H loops on CO2+ concentration in compounds enabled their candidature for applications in memory devices and magnetic sensors
Disciplines: Física y astronomía
Keyword: Física,
Técnica sol-gel,
Estructura de espinela,
Difracción de rayos X,
Microscopía electrónica de barrido,
Coercitividad,
Remanencia
Keyword: Physics,
Sol-gel technique,
Spinel structure,
X-ray diffraction,
Scanning electron microscopy,
Coercivity,
Remanence
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