| Journal: | Quimica nova |
| Database: | PERIÓDICA |
| System number: | 000313188 |
| ISSN: | 0100-4042 |
| Authors: | Caires, Antonio Carlos Favero1 Mauro, Antonio Eduardo2 Moro, Antonio Carlos Legendre, Alexandre de Oliveira Ananias, Sandra Regina |
| Institutions: | 1Universidade de Mogi das Cruzes, Centro Interdisciplinar de Investigacao Bioquimica, Mogi das Cruzes, Sao Paulo. Brasil 2Universidade Estadual Paulista "Julio de Mesquita Filho", Instituto de Quimica, Araraquara, Sao Paulo. Brasil |
| Year: | 2006 |
| Season: | Jul |
| Volumen: | 29 |
| Number: | 4 |
| Pages: | 750-754 |
| Country: | Brasil |
| Language: | Portugués |
| Document type: | Artículo |
| Approach: | Experimental |
| English abstract | This work deals with the use of the cyclometallated compound [Pd(dmba)(N3)(PPh3)] in homogeneous catalytic processes comprising the reductive N-carbonylation of nitrobenzene and p-nitrotoluene to ethyl-phenylcarbamate and ethyl-4-methylphenylcarbamate, respectively. The cyclopalladated compound was also employed in the synthesis of urea derivatives by reacting p-nitrotoluene and m-nitrotoluene, respectively, with p-toluidine and and m-chloroaniline |
| Disciplines: | Química |
| Keyword: | Química organometálica, Catálisis homogénea, Ciclopaladado, Carbonilación, Nitroarenos, Carbamatos |
| Keyword: | Chemistry, Organometallic chemistry, Homogeneous catalysis, Cyclopalladated, Carbonylation, Nitroarenes, Carbamates |
| Full text: | Texto completo (Ver HTML) |
