Fluidos supercriticos em quimica analitica. I. Cromatografia com fluido supercritico: conceitos termodinamicos



Document title: Fluidos supercriticos em quimica analitica. I. Cromatografia com fluido supercritico: conceitos termodinamicos
Journal: Quimica nova
Database: PERIÓDICA
System number: 000197782
ISSN: 0100-4042
Authors: 1

Institutions: 1Universidade de Sao Paulo, Instituto de Quimica de Sao Carlos, Sao Carlos, Sao Paulo. Brasil
Year:
Season: Jul-Ago
Volumen: 24
Number: 4
Pages: 509-515
Country: Brasil
Language: Portugués
Document type: Artículo
Approach: Teórico
English abstract Under the chromatographic point of view, the physico-chemical properties of a supercritical fluid are intermediate to those of the gases and liquids. Many times they approach the best features of each one, as for example, the solubilization power of liquids and low viscosity of gases. The thermodynamic definitions and main physico-chemical features of a supercritical fluid will be presented in this article. The use of supercritical fluids in analytical chemistry has been extremely modest in Brazil, even considering the enormous potential of their applications, and their use in several techniques, such as chromatography (SFC) and supercritical fluid extration (SFE). This article series is intended to discuss the historical evolution, instrumentation features and potential and limitations of the supercritical fluid use in analytical chemistry. A special focus will be centered on chromatography and extration techniques using supercritical fluids
Disciplines: Química
Keyword: Fisicoquímica y química teórica,
Química analítica,
Fluidos supercríticos,
Cromatografía,
Cromatografía con fluidos supercríticos
Keyword: Chemistry,
Analytical chemistry,
Physical and theoretical chemistry,
Supercritical fluids,
Chromatography,
Supercritical fluid chromatography
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