Journal: | Quimica nova |
Database: | PERIÓDICA |
System number: | 000197782 |
ISSN: | 0100-4042 |
Authors: | Carrilho, Emanuel1 Tavares, Maria Cecilia Lancas, Fernando M |
Institutions: | 1Universidade de Sao Paulo, Instituto de Quimica de Sao Carlos, Sao Carlos, Sao Paulo. Brasil |
Year: | 2001 |
Season: | Jul-Ago |
Volumen: | 24 |
Number: | 4 |
Pages: | 509-515 |
Country: | Brasil |
Language: | Portugués |
Document type: | Artículo |
Approach: | Teórico |
English abstract | Under the chromatographic point of view, the physico-chemical properties of a supercritical fluid are intermediate to those of the gases and liquids. Many times they approach the best features of each one, as for example, the solubilization power of liquids and low viscosity of gases. The thermodynamic definitions and main physico-chemical features of a supercritical fluid will be presented in this article. The use of supercritical fluids in analytical chemistry has been extremely modest in Brazil, even considering the enormous potential of their applications, and their use in several techniques, such as chromatography (SFC) and supercritical fluid extration (SFE). This article series is intended to discuss the historical evolution, instrumentation features and potential and limitations of the supercritical fluid use in analytical chemistry. A special focus will be centered on chromatography and extration techniques using supercritical fluids |
Disciplines: | Química |
Keyword: | Fisicoquímica y química teórica, Química analítica, Fluidos supercríticos, Cromatografía, Cromatografía con fluidos supercríticos |
Keyword: | Chemistry, Analytical chemistry, Physical and theoretical chemistry, Supercritical fluids, Chromatography, Supercritical fluid chromatography |
Full text: | Texto completo (Ver HTML) |