Efeito dos ácidos hexenurônicos e da lignina no desempenho da ozonólize, em diferentes pHs da reação



Document title: Efeito dos ácidos hexenurônicos e da lignina no desempenho da ozonólize, em diferentes pHs da reação
Journal: Quimica nova
Database: PERIÓDICA
System number: 000313161
ISSN: 0100-4042
Authors: 1
2
Institutions: 1Universidade Estadual Paulista "Julio de Mesquita Filho", Departamento Engenharia Industrial Madeireira, Itapeva, Sao Paulo. Brasil
2Universidade Federal de Vicosa, Departamento Engenharia Florestal, Vicosa, Minas Gerais. Brasil
Year:
Season: Sep
Volumen: 29
Number: 5
Pages: 922-925
Country: Brasil
Language: Portugués
Document type: Artículo
Approach: Experimental, aplicado
English abstract The effect of pH on the performance of the ozonolysis stage in pulp production was evaluated for conventional and acid treated brown and oxygen delignified eucalyptus kraft pulps. The objective was to determine separately the effects of lignin and hexenuronic acid on the performance of the ozonolysis stage. The reaction of ozone with hexenuronic acid is less sensitive to pH than the reaction of ozone with lignin. The efficiency and the selectivity of the reaction of ozone with pulp decreases after removal of hexenuronic acids. Increasing up to 7.0 the pH during the ozonolysis is viable in the sequence Z/D(EOP)D, resulting in savings of H2SO4 (8,5 kg/tsa) and NaOH (5 kg/tsa), but is not recommended in the sequence Z/ED(PO)
Disciplines: Química,
Agrociencias
Keyword: Química industrial,
Silvicultura,
Pulpa kraft,
Ozonólisis,
Delignificación,
Acidos hexenurónicos,
pH
Keyword: Chemistry,
Agricultural sciences,
Industrial chemistry,
Silviculture,
Kraft pulp,
Ozonolysis,
Delignification,
Hexenuronic acids,
pH
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