Journal: | Quimica nova |
Database: | PERIÓDICA |
System number: | 000197836 |
ISSN: | 0100-4042 |
Authors: | Lima, Geraldo M. de1 |
Institutions: | 1Universidade Federal de Minas Gerais, Departamento de Quimica, Belo Horizonte, Minas Gerais. Brasil |
Year: | 2001 |
Season: | Jul-Ago |
Volumen: | 24 |
Number: | 4 |
Pages: | 526-530 |
Country: | Brasil |
Language: | Portugués |
Document type: | Artículo |
Approach: | Teórico, divulgación |
English abstract | This paper provides a brief review of the chemistry of cyclopentadienyl Sn(II) derivatives which includes the preparation, the molecular structure and reactivity associated with such bis-sandwich tin(II) species. It is compared structural and spectroscopic results and it is also discussed how the nature of the cyclopentadienyl ring bonded to the Sn centre plays an important role in the structural and stability features of the derivatives. Bulk rings such as C5HPri4- , C5Bz5-, C5Me4SiMe2But- and C5Ph5- render air-stable and parallel ring-bonded compounds |
Disciplines: | Química |
Keyword: | Química organometálica, Estaño, Derivados cilopentadienílicos, Compuestos organometálicos |
Keyword: | Chemistry, Organometallic chemistry, Tin, Cyclopentadienyl derivatives, Organometallic compounds |
Full text: | Texto completo (Ver HTML) |