Journal: | Materials research |
Database: | PERIÓDICA |
System number: | 000312422 |
ISSN: | 1516-1439 |
Authors: | Rocha, I.S1 Malmonge, L.F2 Mattoso, L.H.C Gregorio-Junior, R |
Institutions: | 1Universidade Federal de Sao Carlos, Sao Carlos, Sao Paulo. Brasil 2Universidade Estadual Paulista "Julio de Mesquita Filho", Departamento de Fisica e Quimica, Ilha Solteira, Sao Paulo. Brasil |
Year: | 1999 |
Season: | Abr |
Volumen: | 2 |
Number: | 2 |
Pages: | 63-66 |
Country: | Brasil |
Language: | Inglés |
Document type: | Artículo |
Approach: | Descriptivo |
English abstract | The effect of the addition of small amounts of doped and undoped poly(o-methoxyaniline) (POMA) on the morphology of melt crystallized PVDF was investigated by means of polarized light optical microscopy. Undoped POMA (POMA-EB) inhibits nucleation and growth of non ringed spherulites, partially formed by the polar gphase, whereas POMA doped with toluene sulfonic acid (POMA-TSA) favors this process. Moreover, the doping of POMA increases the miscibility between the components of the PVDF/POMA blends, resulting in more homogeneous films. A possible cause of this miscibility increase and for the favoring of the polar gphase, is the higher polarity of the POMA chains as a result of the doping |
Disciplines: | Química, Ingeniería |
Keyword: | Química de polímeros, Ingeniería de materiales, Polímeros conductores, Cristalización, Fluoruro de polivinilideno |
Keyword: | Chemistry, Engineering, Polymer chemistry, Materials engineering, Conducting polymers, Crystallization, Polyvinylidenefluoride |
Full text: | Texto completo (Ver HTML) |