Oxidation of some organic diols with trialkylammonium fluorochromates(VI), R3NH[CrO3F], (R= CH3, C2H5, C3H7 and C4H9) at room temperature and under microwave condition
Document title: Oxidation of some organic diols with trialkylammonium fluorochromates(VI), R3NH[CrO3F], (R= CH3, C2H5, C3H7 and C4H9) at room temperature and under microwave condition
Journal: Journal of the Mexican Chemical Society
Database: PERIÓDICA
System number: 000373967
ISSN: 1665-9686
Authors: 1
1
1
1
Institutions: 1Islamic Azad University, Department of Chemistry, Teherán. Irán
Year:
Season: Abr-Jun
Volumen: 53
Number: 2
Country: México
Language: Inglés
Document type: Artículo
Approach: Experimental, analítico
Spanish abstract Se describe un método eficiente y suave para la mono–oxidación de dioles a los hidroxialdehidos correspondientes con fluorocromatos(VI) de trialquilamonio, R3NH[CrO3F] (R = CH3, C2H5, C3H7 y C4H9), en solución a temperatura ambiente y en solución bajo irradiación de microondas. La facilidad del procedimiento y la sencillez de la extracción del producto, así como de los tiempos de reacción cortos y los rendimientos elevados, son una muestra de las ventajas de estos reactivos
English abstract A mild and efficient method for the mono–oxidation of diols to the corresponding hydroxyaldehydes with trialkylammonium fluorochromates(VI), R3NH[CrO3F] (R= CH3, C2H5 C3H7 and C4H9), in solution at room temperature, and in solution under microwave radiation, is reported. The easy procedure, simple work–up, short reaction times, and excellent yields are advantages of these reagents
Disciplines: Química
Keyword: Química orgánica,
Fluorocromatos(VI) de trialquilamonio,
Oxidantes,
Oxidación,
Dioles,
Microondas,
Temperatura
Keyword: Chemistry,
Organic chemistry,
Trialkylammonium fluorochromates(VI),
Oxidants,
Oxidation,
Diols,
Microwaves,
Temperature
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