Journal: | Ecletica quimica |
Database: | PERIÓDICA |
System number: | 000366943 |
ISSN: | 0100-4670 |
Authors: | Li, X.H1 Jalbout, A.F2 Xiang, W.D1 |
Institutions: | 1Wenzhou University, College of Chemistry and Materials Engineering, Wenzhou, Zhejiang. China 2Universidad Nacional Autónoma de México, Instituto de Quimica, México, Distrito Federal. México |
Year: | 2008 |
Season: | Abr-Jun |
Volumen: | 33 |
Number: | 2 |
Pages: | 13-19 |
Country: | Brasil |
Language: | Inglés |
Document type: | Artículo |
Approach: | Analítico, descriptivo |
English abstract | A new Cu(II) trimers, [Cu3(dcp)2(H2O)8]. 4DMF, with the ligand 3,5-pyrazoledicarboxylic acid monohydrate (H3dcp) has been prepared by solvent method. Its solid-state structure has been characterized by elemental analysis, thermal analysis (TGA and DSC), and single crystal X-ray diffraction. X-ray crystallographic studies reveal that this complex has extended 1-D,2-D and 3-D supramolecular architectures directed by weak interactions (hydrogen bond and aromatic π-π stacking interaction) leading to a sandwich solid-state structure |
Disciplines: | Química, Física y astronomía |
Keyword: | Fisicoquímica y química teórica, Química inorgánica, Física de materia condensada, Complejos de cobre, Química supramolecular, Interacción π–π |
Keyword: | Chemistry, Physics and astronomy, Inorganic chemistry, Physical and theoretical chemistry, Condensed matter physics, Copper complexes, Crystal structure, Supramolecular chemistry, π–π interaction |
Full text: | Texto completo (Ver PDF) |