Tuning luminescence of 3d transition-metal doped quantum particles: Ni+2: CdS and Fe+3: CdS



Document title: Tuning luminescence of 3d transition-metal doped quantum particles: Ni+2: CdS and Fe+3: CdS
Journal: Brazilian journal of physics
Database: PERIÓDICA
System number: 000330158
ISSN: 0103-9733
Authors: 1
1
2
Institutions: 1Malek-Ashtar University of Technology, Faculty of Sciences, Isfahán. Irán
2Shahed University, Department of Physics, Teherán. Irán
Year:
Season: Sep
Volumen: 40
Number: 3
Pages: 301-305
Country: Brasil
Language: Inglés
Document type: Artículo
Approach: Analítico, descriptivo
English abstract The room-temperature photoluminescence of Cd1-xMxS (M=Ni, Fe) nanoparticles were investigated. Compared with the photoluminescence of CdS which peaks at 475 nm, the photoemission of CdS:Fe nanoparticles was peaking at 537 nm because of Fe acting as luminescent centers. On the other hand, the green emission (503 nm) of CdS:Ni attributed to the 1T2g(D)→ 3A2g(F) raditive transition. With the increase of the Ni+2 concentration, photoluminescence intensity is increased while by Fe replacement with Cd ions, PL intensity is decreased. Relative to bulk crystals, due to the quantum confinement effect the band gap of CdS clusters is significantly blue-shifted with decreasing cluster size. CdS nanoclusters present a mixed hexagonal/cubic structure and with increasing doping concentration the peaks position of doped CdS shifts to higher angle
Disciplines: Física y astronomía
Keyword: Física,
Física de materia condensada,
Optica,
Nanopartículas,
Propiedades ópticas,
Fotoluminiscencia,
Estado sólido
Keyword: Physics and astronomy,
Condensed matter physics,
Optics,
Physics,
Nanoparticles,
Optical properties,
Solid state
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