| Journal: | Brazilian journal of physics |
| Database: | PERIÓDICA |
| System number: | 000330194 |
| ISSN: | 0103-9733 |
| Authors: | Ji-Zi Lin1 |
| Institutions: | 1Jiangsu University of Science and Technology, Department of Physics, Zhangjiagang. China |
| Year: | 2010 |
| Season: | Sep |
| Volumen: | 40 |
| Number: | 3 |
| Pages: | 344-47 |
| Country: | Brasil |
| Language: | Inglés |
| Document type: | Artículo |
| Approach: | Experimental |
| English abstract | The electron paramagnetic resonance(EPR) parameters g-factors gi(i = x,y,z) and the hyperfine structure constants Ai for the substitutional Mo5+ in rutile are theoretically studied from the perturbation formulas of these parameters for a d1 ion in a rhombically compressed octahedron. On the basis of the studies, The oxygen octahedron around Mo5+ is found to transform from the original elongation on the host Ti4+ site to compression in the impurity center due to the Jahn-Teller effect. The calculated EPR parameters based on the above local structure in this work are in good agreement with the experimental data |
| Disciplines: | Física y astronomía |
| Keyword: | Física, Física de materia condensada, Física de partículas y campos cuánticos, Resonancia paramagnética electrónica, Cristales, Giros, Mo5+, Rutilo |
| Keyword: | Physics and astronomy, Condensed matter physics, Particle physics and quantum fields, Physics, Electron paramagnetic resonance, Crystal field, Spin hamiltonians, Mo5+, Rutile(TiO2) |
| Full text: | Texto completo (Ver HTML) |
