Preparation of a carbon molecular sieve and application to separation of N2, O2 and CO2 in a fixed bed



Document title: Preparation of a carbon molecular sieve and application to separation of N2, O2 and CO2 in a fixed bed
Journal: Brazilian journal of chemical engineering
Database: PERIÓDICA
System number: 000308857
ISSN: 0104-6632
Authors: 1

Institutions: 1Universidade Federal de Santa Catarina, Departamento de Engenharia Quimica e Engenharia de Alimentos, Florianopolis, Santa Catarina. Brasil
Year:
Season: Mar
Volumen: 20
Number: 1
Pages: 75-80
Country: Brasil
Language: Inglés
Document type: Artículo
Approach: Experimental, aplicado
English abstract The emission of CO2 from power plants that burn fossil fuels is the major cause of the accumulation of CO2 in the atmosphere. The separation of CO2 from CO2/air mixtures can play a key role in alleviating this problem. This separation can be carried out by using suitable adsorbents, such as carbon molecular sieves. In this work, a CMS was prepared by deposition of polyfurfuryl alcohol polymer on activated carbon. After deposition of the polymer, the material was carbonized at 800ºC for 2 hours. This material was used to separate O2/N2 mixtures and CO2 in a fixed bed at room temperature. Experimental breakthrough curves obtained were fitted to theoretical models in order to establish the main mechanisms of mass transfer. The breakthrough curves showed that it is possible to separate O2, N2 and CO2. The shape of the breakthrough curves was not influenced by the total flow, indicating that the gas contact for the gas mixture was good. The experimental data were fitted to theoretical models and it was established that the main mechanism of mass transfer was intraparticle diffusion
Disciplines: Ingeniería
Keyword: Ingeniería ambiental,
Ingeniería química,
Separación de gases,
Dióxido de carbono,
Tamiz de carbón molecular,
Carbón activado
Keyword: Engineering,
Chemical engineering,
Environmental engineering,
Gas separation,
Carbon dioxide,
Carbon molecular sieve,
Activated carbon
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