Dissociation-ionization and ionization-dissociation by multiphoton absorption of acetaldehyde at 266 and 355 nm. Dissociation pathways



Document title: Dissociation-ionization and ionization-dissociation by multiphoton absorption of acetaldehyde at 266 and 355 nm. Dissociation pathways
Journal: Revista mexicana de física
Database: PERIÓDICA
System number: 000404274
ISSN: 0035-001X
Authors: 1
2
2
2
Institutions: 1Universidad Industrial de Santander, Facultad de Ciencias, Bucaramanga, Santander. Colombia
2Universidad Nacional Autónoma de México, Instituto de Ciencias Físicas, Cuernavaca, Morelos. México
Year:
Season: May-Jun
Volumen: 62
Number: 3
Pages: 206-212
Country: México
Language: Inglés
Document type: Artículo
Approach: Analítico, teórico
English abstract The experimental results from the interaction of a sample of acetaldehyde (CH3 CHO) with laser radiation at intensities between 109 and 1011 Wcm−2 and wavelengths of 266 and 355 nm are reported. As a result of multiple photon absorption, cations from ionization-dissociation (I-D) or dissociation-ionization (D-I) processes, were detected using a reflectron time of flight mass spectrometer. The processes I-D is predominant at 355 nm and D-I is predominant at 266 nm. The formation of different ions is discussed. From analysis of the ratios between the ion currents [I(CH3CO+)+I(CO+)]/[ I(CH+ 3 )+I(HCO+)], originated from the C-C bond or from the C-H bond breaking at different laser intensities, the predominant channels are determined
Disciplines: Física y astronomía
Keyword: Física atómica y molecular,
Acetaldehído,
Fotoionización,
Fotodisociación,
Procesos multifotones,
Disociación molecular
Keyword: Physics and astronomy,
Atomic and molecular physics,
Acetaldehyde,
Photoionization,
Photodissociation,
Multiphoton processes,
Molecular dissociation
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