Analysis of the mechanical properties and characterization by solid state 13C NMR of recycled EVA copolymer/silica composites



Título del documento: Analysis of the mechanical properties and characterization by solid state 13C NMR of recycled EVA copolymer/silica composites
Revista: Materials research
Base de datos: PERIÓDICA
Número de sistema: 000312867
ISSN: 1516-1439
Autores: 1
2
3
4
Instituciones: 1Ministerio da Ciencia e Tecnologia, Observatorio Nacional, Rio de Janeiro. Brasil
2Universidade do Estado do Rio de Janeiro, Instituto Politecnico, Nova Friburgo, Rio de Janeiro. Brasil
3Petroleo Brasileiro S.A., Rio de Janeiro. Brasil
4Pontificia Universidade Catolica do Rio de Janeiro, Rio de Janeiro. Brasil
Año:
Periodo: Jul-Sep
Volumen: 8
Número: 3
Paginación: 269-273
País: Brasil
Idioma: Inglés
Tipo de documento: Nota breve o noticia
Enfoque: Experimental
Resumen en inglés The incorporation of micrometer sized silica particles on poly (ethylene-co-vinyl acetate) - EVA - residues from the footwear industry was evaluated. The effects of the processing parameters - temperature and mixing ratio - on the mechanical behavior of molded plates of neat recycled EVA and EVA/silica composites were also investigated. The mechanical properties measured by the tensile test, the fractographic analysis by scanning electron microscopy (SEM), and the 13C Nuclear Magnetic Resonance (NMR) showed a reduced EVA to silica compatibility. Therefore, incorporation of untreated silica to recycled EVA copolymer produced a slight decrease on the mechanical performance of EVA/silica composites in respect to neat EVA copolymer. The NMR analysis also shows that the crosslinking process on recycled EVA may be occurring at the carbonyl group
Disciplinas: Ingeniería,
Química
Palabras clave: Ingeniería ambiental,
Ingeniería mecánica,
Química de polímeros,
Residuos industriales,
Calzado,
Reciclaje,
Propiedades mecánicas,
Sílice,
Copolímeros
Keyword: Engineering,
Chemistry,
Environmental engineering,
Mechanical engineering,
Polymer chemistry,
Industrial wastes,
Footwear,
Mechanical properties,
Silica,
Copolymers,
Recycling
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