Theoretical Study of the Dynamic Stark Effect on Dissociation of CsI



Título del documento: Theoretical Study of the Dynamic Stark Effect on Dissociation of CsI
Revista: Brazilian journal of physics
Base de datos: PERIÓDICA
Número de sistema: 000376086
ISSN: 0103-9733
Autores: 1
1
1
Instituciones: 1Liaoning University, Department of Physics, Shenyang, Liaoning. China
Año:
Periodo: Jun
Volumen: 44
Número: 2-3
Paginación: 189-193
País: Brasil
Idioma: Inglés
Tipo de documento: Artículo
Enfoque: Experimental, analítico
Resumen en inglés The influence of the dynamic Stark effect on the dissociation of CsI is theoretically studied by the time-dependent wave-packet method. After a pump pulse induces a dissociating wave packet that propagates through both the ionic channel X0+(Cs +(1 S 0) + I +(1 S 0)) and the covalent channel A0+(Cs(2 S 1/2) + I(2 P 3/2)), a Stark pulse is applied to control the diabatic-dissociation dynamics. The first-order non-resonant non-perturbative dynamic Stark effect gives control over the break up, the dissociation probabilities in the two channels being controlled by the delay between the pump and Stark pulses. With a 720-fs delay, the dissociation probability through channel A is greatly enhanced
Disciplinas: Física y astronomía
Palabras clave: Física atómica y molecular,
Disociación,
Fentoquímica,
Yoduro de cesio,
Espectro fotoelectrónico,
Efecto Stark
Keyword: Physics and astronomy,
Atomic and molecular physics,
Dissociation,
Fentochemistry,
Cesium iodine,
Photoelectron spectrum,
Stark effect
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