Revista: | Brazilian journal of physics |
Base de datos: | PERIÓDICA |
Número de sistema: | 000146844 |
ISSN: | 0103-9733 |
Autores: | Mesquita, Oscar Nassif de1 |
Instituciones: | 1Universidade Federal de Minas Gerais, Belo Horizonte, Minas Gerais. Brasil |
Año: | 1998 |
Periodo: | Dic |
Volumen: | 28 |
Número: | 4 |
Paginación: | 257-266 |
País: | Brasil |
Idioma: | Inglés |
Tipo de documento: | Artículo |
Enfoque: | Analítico |
Resumen en inglés | Liquid crystals have been very fruitful systems to study equilibrium phase transitions. Recently, they have become an important system to study dynamics of first-order phase transitions. The moving nonequilibrium nematic-isotropic interface is a model system to study growth of stable states into metastable states and displays a myriad of dynamical instabilities that, far from equilibrium, drive the system to a scenario of spatio-temporal chaos. We present a mean-field theory for the time evolution of a planar nonequilibrium nematic-isotropic interface for pure liquid crystals using a time dependent Ginzburg-Landau equation, which is one of the simplest approaches to dissipative dynamics. We obtain a theoretical expression for the growth kinetics of the nematic phase into a metastable isotropic phase and compare it with our experimental results. In a directional solidification arrangement we study instabilities of the nematic-isotropic interface of the liquid crystal 8CB doped with water and hexachloroethane. The observed instabilities are similar to cellular instabilities that appear during growth of crystal-melt interfaces of binary mixtures. We then compare our results with known theories of morphological instabilities during crystal growth |
Disciplinas: | Física y astronomía |
Palabras clave: | Física de materia condensada, Termodinámica y física estadística, Cristales líquidos, Inestabilidad, Termodinámica, Crecimiento de cristales, Transición de fase, Ecuaciones de Ginzburg-Landau |
Keyword: | Physics and astronomy, Condensed matter physics, Thermodynamics and statistical physics, Liquid crystals, Instability, Thermodynamics, Crystal growth, Phase transition, Ginzburg-Landau equations |
Texto completo: | Texto completo (Ver HTML) |