Liquid - liquid equilibria of the water + butyric acid + decanol ternary system



Título del documento: Liquid - liquid equilibria of the water + butyric acid + decanol ternary system
Revista: Brazilian journal of chemical engineering
Base de datos: PERIÓDICA
Número de sistema: 000309052
ISSN: 0104-6632
Autores: 1
Instituciones: 1Istanbul University, School of Engineering, Estambul. Turquía
Año:
Periodo: Sep
Volumen: 23
Número: 3
Paginación: 365-374
País: Brasil
Idioma: Inglés
Tipo de documento: Artículo
Enfoque: Experimental, aplicado
Resumen en inglés Liquid-liquid equilibrium (LLE) data for the water + butyric acid + decanol ternary system were determined experimentally at temperatures of 298.15, 308.15 and 318.15 K. Complete phase diagrams were obtained by determining the solubility curve and the tie lines. The reliability of the experimental tie line data was confirmed with the Othmer-Tobias correlation. The UNIFAC method was used to predict the phase equilibrium of the system using the interaction parameters for groups CH3, CH2, COOH, OH and H2O determined experimentally. Distribution coefficients and separation factors were evaluated for the immiscibility region
Disciplinas: Química
Palabras clave: Química orgánica,
Ingeniería química,
Equilibrio líquido-líquido,
Acido butírico,
Decanol
Keyword: Chemistry,
Organic chemistry,
Chemical engineering,
Liquid-liquid equilibrium,
Butyric acid,
Decanol
Texto completo: Texto completo (Ver HTML)