Synthesis and magnetic characterization of LaMnO3 nanoparticles



Título del documento: Synthesis and magnetic characterization of LaMnO3 nanoparticles
Revista: Revista mexicana de física
Base de datos: PERIÓDICA
Número de sistema: 000384008
ISSN: 0035-001X
Autores: 1
1
1
Instituciones: 1Universidad de Los Andes, Facultad de Ciencias, Mérida. Venezuela
Año:
Periodo: May-Jun
Volumen: 61
Número: 3
Paginación: 170-181
País: México
Idioma: Inglés
Tipo de documento: Artículo
Enfoque: Analítico, teórico
Resumen en inglés LaMnO3 Nanoparticles systems were prepared by the sol-gel auto-combustion method, in order to analyze the structure and magnetic behavior presented by the compound prepared following a new alternative route of synthesis. Structural characterization, morphology and crystallite size was performed by X-ray diffraction (XRD), infrared spectroscopy (IR) and electron microscopy (TEM). The XRD study together with a Rietveld analysis showed that the LaMnO3 compound crystallized in a perovskite hexagonal structure. The IR spectra showed that the compound has tensile energy bands in the Mn-O-Mn bonds related with the octahedron MnO6; which are attributed to a characteristic vibration of the ABO3 perovskite. An estimated size and morphological analysis was carried out by applying the Scherrer's formula and using Transmission Electron Microscopy (TEM), revealing non-spherical shape and particle sizes between 13 nm and 18 nm. The magnetic measurements M(T) were performed by using zero-field-cooled (ZFC) and field-cooled (FC) protocols which revealed a positive Weiss temperature indicating the presence of ferromagnetic interactions with a Curie temperature, TC = 150 K
Disciplinas: Física y astronomía
Palabras clave: Física de materia condensada,
Sol-gel,
Autocombustión,
Temperatura de Curie,
Magnetización,
Manganitas,
Ferromagnetismo,
Perovskita
Keyword: Physics and astronomy,
Condensed matter physics,
Sol-gel,
Autocombustion,
Curie temperature,
Magnetization,
Manganites,
Nanoparticles,
Ferromagnetism,
Perovskite
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