The application of the Diels-Alder reaction to polymer syntheses based on furan/maleimide reversible couplings



Título del documento: The application of the Diels-Alder reaction to polymer syntheses based on furan/maleimide reversible couplings
Revista: Polimeros (Sao Carlos)
Base de datos: PERIÓDICA
Número de sistema: 000314208
ISSN: 1678-5169
Autores: 1
Instituciones: 1Universidade de Aveiro, Departamento de Quimica, Aveiro. Portugal
Año:
Periodo: Abr-Jun
Volumen: 15
Número: 2
Paginación: 95-101
País: Brasil
Idioma: Inglés
Tipo de documento: Artículo
Enfoque: Experimental, aplicado
Resumen en inglés The furan heterocycle is a dienic reagent particularly suitable for the Diels-Alder reaction and maleimides represent a typical family of complementary reagents because of their strong dienophilic character. This paper reviews critically the studies devoted to the exploitation of the Diels Alder reaction between those moieties to synthesise macromolecular materials possessing different structures and properties. The most relevant approaches in this field are (i) polycondensation reactions calling upon A-A and B-B monomers and (ii) reversible cross-linking of linear polymers bearing pendant furan or maleimide moieties, based on the temperature sensitivity of the Diels-Alder equilibrium
Disciplinas: Química
Palabras clave: Química de polímeros,
Polimerización,
Furanos,
Reacción de Diels Alder,
Maleimidas,
Policondensación
Keyword: Chemistry,
Polymer chemistry,
Polymerization,
Furanes,
Diels-Alder reaction,
Maleimides,
Polycondensation
Texto completo: Texto completo (Ver HTML)