Synthesis of Zr-Si-O-N phases by carbonitriding reaction. Characterization of crystalline phases using the Rietveld method



Título del documento: Synthesis of Zr-Si-O-N phases by carbonitriding reaction. Characterization of crystalline phases using the Rietveld method
Revista: Materials research
Base de datos: PERIÓDICA
Número de sistema: 000312467
ISSN: 1516-1439
Autores: 1

Instituciones: 1Universidad Nacional de La Plata, Centro de Tecnología de Recursos Minerales y Cerámica, La Plata, Buenos Aires. Argentina
Año:
Volumen: 4
Número: 2
Paginación: 107-111
País: Brasil
Idioma: Inglés
Tipo de documento: Artículo
Enfoque: Experimental
Resumen en inglés Zirconium compounds are of great interest for ceramic application due to their excellent thermal and mechanical properties. Zirconium phases of the system Zr-O-C-N were obtained using carbonitriding reactions of zircon mineral (ZrO2.SiO2), under different reaction conditions. The reaction products were studied by X-ray diffraction (XRD) using the Rietveld method. Silicon was employed as internal standard. Zirconium compounds formed were m-ZrO2 (monoclinic), b”-zirconium oxynitride and a cubic Zr(C,N,O) phase whose lattice parameter ao depends on the composition. The crystallite sizes of the three zirconium phases were determined also by XRD. The minority phases present are the ones of the Si-O-N-C system. The reaction conditions employed allows to obtain reaction products with low or without silicon content
Disciplinas: Ingeniería
Palabras clave: Ingeniería de materiales,
Ingeniería industrial,
Ingeniería química,
Circonio,
Cerámica,
Propiedades térmicas,
Propiedades mecánicas,
Método de Rietveld
Keyword: Engineering,
Chemical engineering,
Industrial engineering,
Materials engineering,
Zirconium,
Ceramics,
Thermal properties,
Mechanical properties,
Rietveld method
Texto completo: Texto completo (Ver HTML)