Optimization of the operative conditions for heteropolyacids synthesis through ion exchange



Título del documento: Optimization of the operative conditions for heteropolyacids synthesis through ion exchange
Revista: Materials research
Base de datos: PERIÓDICA
Número de sistema: 000312880
ISSN: 1516-1439
Autores: 1

Instituciones: 1Universidad Nacional de La Plata, Centro de Investigación y Desarrollo en Ciencias Aplicadas, La Plata, Buenos Aires. Argentina
Año:
Periodo: Jul-Sep
Volumen: 8
Número: 3
Paginación: 351-355
País: Brasil
Idioma: Inglés
Tipo de documento: Nota breve o noticia
Enfoque: Experimental
Resumen en inglés Phospho-tungstic and phospho-molybdic Wells-Dawson heteropolyacids, H6P2W18O62 .xH2O and H6P2Mo18O62 .xH2O respectively, were synthesized through ion exchange with a higher yield (~ 90%) than the conventional organic route (~ 70%). Pure, non-degraded heteropolyacids are obtained when the corresponding ammonium salt [(NH4)6P2W18 O62.13H2O or (NH4)6P2Mo18 O62.12H2O] is kept in contact with an acid resin [about (1:0.8) salt:resin weight ratio] up to three days. The use of an organic media instead of an aqueous media greatly favors the completeness of the exchange
Disciplinas: Ingeniería,
Química,
Física y astronomía
Palabras clave: Ingeniería de materiales,
Ingeniería química,
Química industrial,
Física de materia condensada,
Catalizadores,
Intercambio iónico,
Cambio de fase,
Temperatura
Keyword: Engineering,
Chemistry,
Physics and astronomy,
Chemical engineering,
Materials engineering,
Industrial chemistry,
Condensed matter physics,
Catalysts,
Ion exchange,
Phase change,
Temperature
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