| Revista: | Journal of applied research and technology |
| Base de datos: | PERIÓDICA |
| Número de sistema: | 000427617 |
| ISSN: | 1665-6423 |
| Autores: | Lopez Luna, Mauricio-mauricio.lopez.luna.chem.eng@gmail.com1 Cedeño Caero, Luis1 |
| Instituciones: | 1Universidad Nacional Autónoma de México, Facultad de Química, Ciudad de México. México |
| Año: | 2018 |
| Periodo: | Dic |
| Volumen: | 16 |
| Número: | 6 |
| País: | México |
| Idioma: | Inglés |
| Tipo de documento: | Artículo |
| Enfoque: | Experimental, aplicado |
| Resumen en inglés | Tungsten oxide based catalysts for the oxidative desulfurization (ODS) process of dibenzothiophene compounds using H2O2 as oxidizing agent were studied. Catalysts were characterized by TPR-H2, SEM-EDS, XRD, N2-physisorption and Raman spectroscopy. Different surface tungsten oxide species were detected and related to the ODS activity, furthermore, the predominance of the surface tungsten oxide species was associated with the tungsten loading. Moreover, in some catalysts, WO3 crystals were detected and their role in the performance of the catalysts was studied too. Finally, the catalysts were partially reduced and tested in the ODS reaction, the reduced catalysts exhibited high activity and an improvement of H2O2 to sulfones yield |
| Disciplinas: | Ingeniería, Química |
| Palabras clave: | Ingeniería química, Desulfuración oxidativa, Catalizadores, Oxido de tungsteno, Diesel, Dibenzotiofeno |
| Keyword: | Chemical engineering, Oxidative desulfurization, Catalysts, Tungsten oxide, Diesel, Dibenzothiophene |
| Texto completo: | Texto completo (Ver HTML) Texto completo (Ver PDF) |
