Variational description of the 3-body Coulomb problem through a correlated Eckart-Gaussian wavefunction



Título del documento: Variational description of the 3-body Coulomb problem through a correlated Eckart-Gaussian wavefunction
Revista: Brazilian journal of physics
Base de datos: PERIÓDICA
Número de sistema: 000309272
ISSN: 0103-9733
Autores: 1
1
Instituciones: 1Benemérita Universidad Autónoma de Puebla, Instituto de Física, Puebla. México
Año:
Periodo: Sep
Volumen: 29
Número: 3
Paginación: 529-540
País: Brasil
Idioma: Inglés
Tipo de documento: Artículo
Enfoque: Aplicado, analítico
Resumen en inglés The quantum mechanical problem posed by the internal motion of three particles subject to Coulomb interactions is variationally solved by means of an Eckart-Gaussian (EG) ansatz that exhibits an exponential behavior with respect to the radial coordinates {r1,r2}, and a harmonic Gaussian-type dependence on the interparticle distance r12, thereby providing explicit correlation. The proposed wavefunction is of the form (e-a1r1-b1r2 + e-b2r1 -a2r2) rl12 e-g( r12-u0)2, through which ground state energies are calculated for a few two-electron atoms-considering finite nuclear mass effects-and molecular ions corresponding to electronic and mesonic systems. The physical interpretation and advantages of the EG wavefunction are discussed in terms of the relative masses of the particles in the analyzed systems. A useful application of the variational method is presented where the underlying structure of the 3-body wavefunction combines an atomic- and a molecular-like description of the system. The obtained energies agree with the exact results within 10-4 - 10-2 Hartrees
Disciplinas: Física y astronomía
Palabras clave: Física,
Fuerzas de Coulomb,
Problema de tres cuerpos,
Mecánica cuántica,
Iones moleculares
Keyword: Physics and astronomy,
Physics,
Coulomb forces,
Three-body problem,
Molecular ions
Texto completo: Texto completo (Ver HTML)