Theoretical studies of the EPR parameters for Ni2+ and Co+ in MgO



Título del documento: Theoretical studies of the EPR parameters for Ni2+ and Co+ in MgO
Revista: Brazilian journal of physics
Base de datos: PERIÓDICA
Número de sistema: 000330204
ISSN: 0103-9733
Autores: 1
2
1
1
Instituciones: 1University of Electronic Science and Technology of China, Department of Applied Physics, Chengdu, Sichuan. China
2Chinese Academy of Sciences, International Centre for Materials Physics, Shenyang. China
Año:
Periodo: Sep
Volumen: 40
Número: 3
Paginación: 361-364
País: Brasil
Idioma: Inglés
Tipo de documento: Artículo
Enfoque: Experimental
Resumen en inglés The electron paramagnetic resonance (EPR) parameters (g factors and the hyperfine structure constants) for Ni2+ and Co+ in MgO are theoretically studied from the perturbation formulas of these parameters for a 3d8 ion in octahedral crystal-fields. In the computations, the ligand orbital and spin-orbit coupling contributions are taken into account using the cluster approach. The calculated EPR parameters are in good agreement with the experimental data. The larger g factor and the smaller magnitude of the hyperfine structure constant for Ni2+ as compared with those for Co+ can be attributed to the higher spin-orbit coupling coefficient and the lower dipolar hyperfine structure parameter of the former, respectively
Disciplinas: Física y astronomía
Palabras clave: Física,
Física de materia condensada,
Estado sólido,
Impurezas,
Defectos,
Ni2+,
Co+,
MgO
Keyword: Physics and astronomy,
Condensed matter physics,
Physics,
Solid state,
Impurities,
Defects,
Electron paramagnetic resonance,
Ni2+,
Co+,
MgO
Texto completo: Texto completo (Ver HTML)