A comparison of different modeling approaches for the simulation of the transient and steady-state behavior of continuous emulsion polymerizations in pulsed tubular reactors
Título del documento: A comparison of different modeling approaches for the simulation of the transient and steady-state behavior of continuous emulsion polymerizations in pulsed tubular reactors
Revista: Brazilian journal of chemical engineering
Base de datos: PERIÓDICA
Número de sistema: 000308853
ISSN: 0104-6632
Autores: 1
Instituciones: 1Universidade de Sao Paulo, Escola Politecnica, Sao Paulo. Brasil
Año:
Periodo: Mar
Volumen: 19
Número: 1
Paginación: 89-104
País: Brasil
Idioma: Inglés
Tipo de documento: Artículo
Enfoque: Experimental, aplicado
Resumen en inglés Dynamic mathematical models are developed to simulate styrene emulsion polymerization reactions carried out in pulsed tubular reactors. Two different modeling approaches, the tanks-in-series model and the axial dispersion model, are compared. The models developed were validated with experimental data from the literature and used to study the dynamics during transient periods, e.g., the start-up of the reactor and the response to disturbances. The effect of the Peclet number on process variables such as conversion and particle concentration was also verified
Disciplinas: Química
Palabras clave: Química de polímeros,
Ingeniería química,
Polimerización por emulsión,
Reactores tubulares,
Dispersión axial,
Estireno
Keyword: Chemistry,
Polymer chemistry,
Chemical engineering,
Emulsion polymerization,
Tubular reactors,
Axial dispersion,
Styrene
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