Ultrasound assisted synthesis of ZnO nanorods on flexible substrates



Título del documento: Ultrasound assisted synthesis of ZnO nanorods on flexible substrates
Revista: Superficies y vacío
Base de datos: PERIÓDICA
Número de sistema: 000377929
ISSN: 1665-3521
Autores: 1
2
Instituciones: 1Universidad de Concepción, Facultad de Ingeniería, Concepción. Chile
2Universidad Nacional de Colombia, Departamento de Física y Química, Manizales, Caldas. Colombia
Año:
Periodo: Sep
Volumen: 26
Número: 3
Paginación: 100-106
País: México
Idioma: Inglés
Tipo de documento: Artículo
Enfoque: Experimental, aplicado
Resumen en inglés Small hexagonal-shaped ZnO Nanorods (ZnO-NRs) were synthesized on PET (Polyethylene terephthalate)/ITO substrates through a conventional wet chemical method assisted by ultrasound using Zn(NO3)2 and hexamethylenetetramine (HMT) as precursors. The reaction was carried out in three steps: i) ZnO seeds synthesis, ii) ZnO seeds deposition, and iii) ultrasound-assisted unidirectional growth of ZnO-NRs. Aligned ZnO-NRs were characterized by HRTEM, SAED, EF-SEM, UV-Vis and Raman spectroscopy; their lengths and thicknesses ranged 240 - 350 nm and 25 - 80 nm, respectively on PET/ITO substrates. Results indicated that ZnO-NRs were grown on a 200 nm thick ZnO rigid film formed by a dip-coating method which has brittle nature. It could hinder the use of these substrates in the construction of flexible devices. ZnO-NRs/(PET/ITO) transmits a UV-Vis radiation between 50% and 80%, whose variation depends on the synthesis conditions. Optical band-gap of the synthesized material approximately 3.3 eV is independent on the Nanorods' dimensions. Experimental and structural details are also discussed in this work
Disciplinas: Ingeniería
Palabras clave: Ingeniería de materiales,
Ingeniería química,
Nanoestructuras,
Oxido de zinc,
Síntesis química,
Ultrasonido
Keyword: Engineering,
Chemical engineering,
Materials engineering,
Nanostructures,
Zinc oxide,
Chemical synthesis,
Ultrasound
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