Phase equilibria in heterogeneous systems with AxB1-xCyD1-y alloys



Título del documento: Phase equilibria in heterogeneous systems with AxB1-xCyD1-y alloys
Revista: Superficies y vacío
Base de datos: PERIÓDICA
Número de sistema: 000404983
ISSN: 1665-3521
Autors: 1
1
1
Institucions: 1Instituto Politécnico Nacional, Centro de Investigación y de Estudios Avanzados, México, Distrito Federal. México
Any:
Període: Dic
Volum: 16
Número: 4
Paginació: 6-13
País: México
Idioma: Inglés
Tipo de documento: Artículo
Enfoque: Analítico
Resumen en inglés The AxB1−xCyD1− y alloys are the conventional materials of the semiconductor heterostructures for the optoelectronics device applications. The liquid phase epitaxy is one of the methods for preparation of the AxB1−xCyD1− y -based heterostructures. The liquid phase epitaxial processes are fulfilled near thermodynamic equilibrium. Therefore, information on the phase diagram and miscibility gap is necessary for the liquid phase epitaxy growth of the AxB1−xCyD1−y alloys. The phase equilibria in the heterogeneous systems with the AxB1−xCyD1− y alloy in the regular solution model are presented. The heterogeneous equilibria are considered as minimum condition of the Helmholtz free energy of the system that is presented as a canonical ensemble. The strictly regular approximation is used for description of all phases. The interactions between the nearest and next nearest atoms as well as the oscillation movement of the atoms are taken into account. The supposition on random distribution of the cations and anions in their sublattices is used for the configurational entropy. The numerical estimations are fulfilled for the phase diagram consisting of the ( ) In, Ga, Sb, As liquid solution and the xGa xSby As y In 1− 1− alloy lattice matched with the GaSb substrate. The obtained theoretical estimations are in good agreement with the available experimental results
Disciplines Física y astronomía,
Ingeniería
Paraules clau: Física de materia condensada,
Ingeniería de materiales,
Ingeniería electrónica,
Semiconductores,
Optoelectrónica,
Aleaciones,
Indio,
Galio,
Antimonio,
Arsénico
Keyword: Physics and astronomy,
Engineering,
Condensed matter physics,
Electronic engineering,
Materials engineering,
Semiconductors,
Optoelectronics,
Alloys,
Indium,
Gallium,
Antimony,
Arsenic
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