Potassium extraction from the silicate rock Verdete using organic acids



Título del documento: Potassium extraction from the silicate rock Verdete using organic acids
Revista: Scientia Agricola
Base de datos: PERIÓDICA
Número de sistema: 000455481
ISSN: 0103-9016
Autors: 1
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2
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Institucions: 1Universidade Federal de Uberlandia, Instituto de Ciencias Agrarias, Monte Carmelo, Minas Gerais. Brasil
2Universidade Federal de Uberlandia, Faculdade de Engenharia Quimica, Uberlandia, Minas Gerais. Brasil
Any:
Volum: 79
Número: 2
País: Brasil
Idioma: Inglés
Tipo de documento: Artículo
Enfoque: Experimental, analítico
Resumen en inglés Although Brazil is one of the world's leading exporter of agricultural products, the country is highly dependent on the importation of potassic fertilizers. K-bearing silicate rocks are reported as potential solutions to reduce external K dependency. This work evaluated K extraction from silicate Verdete rock, a glauconite-bearing rock containing 10 % of K2O, by solubilization with organic acids. Firstly, Verdete rock was reacted during 3-120 h with solutions of citric or oxalic acid at 2 % (m/v) in Erlenmeyer flasks by shaking. Oxalic acid extracted 6.5 % of K in Verdete, while citric acid extracted 2.3 %. Another experiment was performed to evaluate the effect of various oxalic acid concentrations (2, 4, 6, 8, and 10 %) and differing reaction times (12, 24, 48, and 72 h) on K extraction from Verdete rock. Soluble K concentration nearly doubled with the increase of reaction time from 12 to 72 h, rising from 20 to 37 mg L–1. Increments in K extraction were obtained by increasing oxalic acid concentrations up to 6 % and above this concentration, no significant gain was observed. The X-ray diffraction data showed that K extraction resulted from the formation of oxalate-metal complexes with metals in Verdete rock
Disciplines Agrociencias,
Geociencias
Paraules clau: Fertilización,
Mineralogía, petrología y geoquímica,
Glauconita,
Biolixiviación,
Oxalatos
Keyword: Fertilization,
Mineralogy, petrology and geochemistry,
Glauconite,
Bioleaching,
Oxalate
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