Theoretical studies of the Electron Paramagnetic Resonance parameters and local structure for the trigonal Yb3+ center in YAl3(BO3)4 crystal



Título del documento: Theoretical studies of the Electron Paramagnetic Resonance parameters and local structure for the trigonal Yb3+ center in YAl3(BO3)4 crystal
Revista: Revista mexicana de física
Base de datos: PERIÓDICA
Número de sistema: 000429654
ISSN: 0035-001X
Autors: 1
1
Institucions: 1Chengdu Normal University, College of Physics and Engineering, Chengdu, Sichuan. China
Any:
Període: Ene-Feb
Volum: 65
Número: 1
País: México
Idioma: Inglés
Tipo de documento: Artículo
Enfoque: Analítico, teórico
Resumen en inglés Yttrium aluminium borate crystals have excellent physical and chemical properties. In this paper, the electron paramagnetic resonance g factors g ∥, g ⊥ of Yb3+ and hyperfine structure constants A ∥, A ⊥ of 171Yb3+ and 173Yb3+ isotopes in YAl3(BO3)4 crystal are calculated from the perturbation formulas. The crystal field parameters are obtained from the superposition model and the crystal structure data. The electron paramagnetic resonance parameters for trigonal Yb3+ centers in YAl3(BO3)4 are reasonably explained by considering the defect structures of doped Yb3+ centers. In the calculation, we also find that Yb3+ ion does not exactly reside in Y3+ site, but suffers an angle distortion ∆θ(≈ 3.98o) with C3 axis. The results are discussed
Disciplines Física y astronomía
Paraules clau: Física de materia condensada,
Resonancia paramagnética electrónica,
Teoría del campo de cristal,
Análisis del modelo de superposición
Keyword: Condensed matter physics,
Electron paramagnetic Resonance,
Crystal-field theory,
Superposition model analysis
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