Preparation and chemical characterization of neodymium-doped molybdenum oxide films grown using spray pyrolysis



Título del documento: Preparation and chemical characterization of neodymium-doped molybdenum oxide films grown using spray pyrolysis
Revista: Revista mexicana de física
Base de datos: PERIÓDICA
Número de sistema: 000378374
ISSN: 0035-001X
Autors: 1
2
Institucions: 1Universidad Nacional de Colombia, Departamento de Física, Bogotá. Colombia
2Universidad Nacional de Colombia, Departamento de Química, Bogotá. Colombia
Any:
Període: Mar-Abr
Volum: 60
Número: 2
Paginació: 114-118
País: México
Idioma: Inglés
Tipo de documento: Artículo
Enfoque: Analítico, teórico
Resumen en inglés We studied the crystallinity, morphology, and surface composition of Nd-doped molybdenum oxide films grown on glass slides through spray pyrolysis. After fabrication, the films were subjected to thermal treatment in oxygen for periods ranging from 2 to 20 hours. The films were structurally characterized through X-ray diffraction (XRD), their bulk chemical composition was determined using Energy-Dispersive X-ray analysis (EDX), and their surface composition was determined using X-ray Photoelectron Spectroscopy (XPS). The XRD results show that the films obtained from different dissolution volumes and at substrate temperature of 300° C exhibit the characteristics of the oxygen-deficient molybdenum trioxide Mo9 O26 phase. The films subjected to different thermal treatments exhibit a mixture of Mo9O26 and Mo17O47 phases. EDX study shows the energy belonging to the L line of Nd. Finally, films doped with Nd and subjected to a thermal treatment of 20h were analyzed through XPS, showing the binding energies at the crystalline lattice correspond to Nd2 (MoO4)3 and Nd2Mo2O7
Disciplines Física y astronomía
Paraules clau: Física atómica y molecular,
Películas delgadas,
Atomización pirolítica,
Oxido de molibdeno,
Morfología
Keyword: Physics and astronomy,
Atomic and molecular physics,
Thin films,
Spray pyrolysis,
Molybdenum oxide,
Morphology
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