Orientational relaxation for small wavevectors of rod-like Brownian particles



Título del documento: Orientational relaxation for small wavevectors of rod-like Brownian particles
Revista: Revista mexicana de física
Base de datos: PERIÓDICA
Número de sistema: 000427168
ISSN: 0035-001X
Autors: 1
1
2
Institucions: 1Benemérita Universidad Autónoma de Puebla, Facultad de Ciencias Físico Matemáticas, Puebla. México
2Universidad de las Américas, Departamento de Actuaría, Física y Matemáticas, Cholula, Puebla. México
Any:
Període: Nov-Dic
Volum: 63
Número: 6
País: México
Idioma: Inglés
Tipo de documento: Artículo
Enfoque: Analítico, teórico
Resumen en inglés We present a theorical study of the kinetic orientational relaxation of a colloidal monodispersed system of stiff and long rods, for small wavevectors. This process is described by the dynamic structure factor. The relationship between this factor with the fluctuations of the second order parameter is provided in the limit of wavevectors going to zero. The second order parameter is computed with the Smoluchowski formalism, neglecting hydrodynamic interactions, and using the Maier-Saupe potential for the rods interaction. Considering suitable properties, the isothermal orientation susceptibility proposed is able to localize the isotropic and nematic concentrations in qualitative agreement with well known computer simulations results. At relaxation our model predicts a single value for the maximum of the orientation property proposed, which it is reached at different times, according to the concentration
Disciplines Física y astronomía
Paraules clau: Física de materia condensada,
Relajación orientativa,
Transición de fase,
Parámetro de segundo orden,
Ecuación de Smoluchowski
Keyword: Condensed matter physics,
Orientational relaxation,
Phase transition,
Second order parameter,
Smoluchowski equation
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