Luminescent characteristics of Eu2+/Li+ doped (La-Al)2O3 phosphors and PMMA films activated with them



Título del documento: Luminescent characteristics of Eu2+/Li+ doped (La-Al)2O3 phosphors and PMMA films activated with them
Revista: Revista mexicana de física
Base de datos: PERIÓDICA
Número de sistema: 000460932
ISSN: 0035-001X
Autors: 1
2
2
3
2
1
2
Institucions: 1Universidad Nacional Autónoma de México, Instituto de Física, Ciudad de México. México
2Instituto Politécnico Nacional, Ciudad de México. México
3Instituto Politécnico Nacional, Centro de Investigación y de Estudios Avanzados, Ciudad de México. México
Any:
Període: Sep-Oct
Volum: 64
Número: 5
Paginació: 447-455
País: México
Idioma: Inglés
Tipo de documento: Artículo
Enfoque: Analítico, teórico
Resumen en inglés The effect of Li co-doping on the blue luminescence of Eu2+ doped (La-Al)2 O3 phosphors and its incorporation into poly (methyl methacrylate) PMMA films are reported. The phosphors were synthesized by a simple two-step process in which the (La-Al)2 O3 powders were obtained by an evaporation method, and the subsequent co-doping with Li+ and Eu2+ were made through a solid state reaction in a reductive atmosphere at 1250°C. The incorporation of those phosphors into PMMA matrix and the synthesis of films with thicknesses between 6 and 12 μm was made by drop-casting. The characteristic blue broad band emission centered at 440 nm associated with the 4f65d1→4F7 transition of Eu2+ ions (CIE coordinates 0.6731, 0.3343) was observed when these powders were excited with 297 nm light. These luminescence intensity was enhanced when Li+ was incorporated as co-dopant up to 320% with respect to those phosphors without Lithium. The luminescent characteristics of these phosphors were preserved when they were embedded into the PMMA films
Disciplines Física y astronomía
Paraules clau: Optica,
Luminiscencia,
Efecto Litio,
Láminas compuestas de PMMA
Keyword: Optics,
Luminescence,
Lithium effect,
PMMA composite films
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